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Sorption properties of tylosin on four different microplastics. Guo Xuetao,Pang Jingwen,Chen Shouyi,Jia Hanzhong Chemosphere After oxidation, abrasion and crushing, microplastics (MPs) can enter the aqueous environment and may adsorb surrounding organic pollutants, altering its migration and spatial distribution. Therefore, an investigation of the sorption properties and mechanism of organic pollutant on MPs can offer a theoretical basis for scientific evaluation of their ecological risks. Using tylosin (TYL) as a model pollutant, the sorption performance of MPs was examined via a series of batch equilibrium experiments which resulted the sorptive removal of TYL on MPs reached equilibrium at 36 h, and the sorption ability of TYL on the MPs followed the order of PE (polyethylene) < PP (polypropylene) < PS (polystyrene) < PVC (polyvinyl chloride). The pseudo-second-order model well fit for the sorption kinetics data, and the adsorption isotherms could be better described by Freundlich equation rather than Langmuir model. Additionally, the initial solution pH and ionic strength played important roles across the adsorption. The sorption procedure of TYL on MPs was dominated by electrostatic interaction, surface complexation and hydrophobic interaction. 10.1016/j.chemosphere.2018.06.100
Hydrophobic sorption behaviors of 17β-Estradiol on environmental microplastics. Liu Xuemin,Xu Jiang,Zhao Yaping,Shi Huahong,Huang Ching-Hua Chemosphere Microplastics (MPs) have been regarded as a vector for contaminants and greatly affect the migration and fate of hydrophobic organic compounds (HOCs) in marine water. In this study, the sorption behavior of 17β-estradiol (E2) on MPs was investigated in marine water system. The sorption capacity of E2 varied greatly with the chemical structures of MPs. The adsorption or partition contribution of E2 sorption on MPs was well quantified with adsorption-partition dual-mode model mechanism. The hydrophobic partition dominantly regulates the sorption of E2 due to the high crystallinity of MPs and high accessibility of amorphous domain of rubbery MPs. Smaller particle size benefits the sorption of E2 on same kind of MPs. The salinity and dissolved organic matter (DOM) have minor effect on E2 sorption by MPs in real marine water. The result shows that the MPs greatly influence the transportation of E2 and cause potential environmental risk to marine ecosystem. 10.1016/j.chemosphere.2019.03.162
Interfacial interaction between diverse microplastics and tetracycline by adsorption in an aqueous solution. Yu Fei,Yang Changfu,Huang Guoqiong,Zhou Tao,Zhao Youcai,Ma Jie The Science of the total environment The accumulation of microplastics in offshore aquaculture waters has gradually become a threat to the survival of marine life, and the combined pollution of microplastics and other pollutants is attracting widespread attention. In this paper, tetracycline (TC) was selected as a typical antibiotic, and its adsorption behavior on the surface of diverse type and different sizes of microplastics was studied to explore their combined pollution in an aqueous solution. The results of isotherm fitting showed that the maximum adsorption capacity and coefficient of polyethylene (PE) were the largest, and the adsorption capacity of PE was the strongest among the three microplastics: polyethylene (PE), polystyrene (PS) and polyvinyl chloride (PVC). With increasing PE particle size, the maximum adsorption capacity and adsorption coefficient of TC showed a significant decreasing trend, with a slight fluctuation in the middle. The presence of Pb, Cr, Cd, and Zn markedly enhanced the adsorption of TC to PE, and Cu could reduce the adsorption of TC to PE. The presence of chloride ions did not affect the adsorption process, which indicated that the adsorption mechanism between TC and microplastics is mainly an ion exchange mechanism. These results showed that the surface properties of microplastics and the chemical properties of the aqueous solution played an important role in the adsorption of TC. This study provides important scientific guidance and a theoretical basis for the study of the interfacial behavior, migration and transformation of marine microplastics. 10.1016/j.scitotenv.2020.137729
Adsorption of phenanthrene and its monohydroxy derivatives on polyvinyl chloride microplastics in aqueous solution: Model fitting and mechanism analysis. Bao Zhen-Zong,Chen Zhi-Feng,Zhong Yuanhong,Wang Guangzhao,Qi Zenghua,Cai Zongwei The Science of the total environment The pervasiveness of microplastics, which can absorb pollutants, has a certain impact on pollutant migration in natural waters. Differences in functional groups, such as the hydroxyl group, of pollutants will affect their adsorption on microplastics. In this study, the adsorption of phenanthrene (PHE) or its monohydroxy derivatives, including 1-hydroxyphenanthrene (1-OHP), 2-hydroxyphenanthrene (2-OHP), 4-hydroxyphenanthrene (4-OHP), and 9-hydroxyphenanthrene (9-OHP), on polyvinyl chloride (PVC, measured mean particle size = 134 μm) microplastics was studied. The adsorption efficiency of PHE was shown to be higher than that of either of OHPs. A better fit for pseudo-second-order and Freundlich isotherm models was obtained, indicating different binding sites on the surface of PVC microplastics. The adsorption processes of PHE and OHPs on PVC microplastics were demonstrated to be exothermic and spontaneous. Combined with FT-IR analysis, theoretical calculation, and comparative adsorption experiments, hydrophobic interaction was the dominant mechanism during the adsorption process. In contrast, electrostatic repulsion, CH/π interaction, and halogen bonding played a minor role, to an extent, in the adsorption of PHE/OHPs on PVC microplastics. These findings indicate the influence of the hydroxyl group on adsorption and improve the understanding of interactions between PVC microplastics and PHE/OHPs. 10.1016/j.scitotenv.2020.142889